Structure, Morphology and Growth of Biogenic Greigite (Fe3S4)
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Low-temperature magnetic properties of greigite (Fe3S4)
[1] We provide comprehensive low-temperature magnetic results for greigite (Fe3S4) across the spectrum from superparamagnetic (SP) to multidomain (MD) behavior. It is well known that greigite has no lowtemperature magnetic transitions, but we also document that it has strong domain-state dependence of magnetic properties at low temperatures. Blocking of SP grains and increasing thermal stabilit...
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The excellent electrochemical performance of greigite (Fe3S4) coupled with its vast abundance and low toxicity make it a good prospect as an anode material for lithium ion batteries (LIBs). In this research, a simple and feasible approach for producing pure phase, small sized, shape-controllable, and stable Fe3S4 nanoplates (NPs) through hot injection of sulfur solution into Fe(iii) solution wa...
متن کاملA comparative DFT study of the mechanical and electronic properties of greigite Fe3S4 and magnetite Fe3O4.
Greigite (Fe3S4) and its analogue oxide, magnetite (Fe3O4), are natural minerals with an inverse spinel structure whose atomic-level properties may be difficult to investigate experimentally. Here, [D. Rickard and G. W. Luther, Chem. Rev. 107, 514 (2007)] we have calculated the elastic constants and other macroscopic mechanical properties by applying elastic strains on the unit cells. We also h...
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[1] We have investigated greigite (Fe3S4) using a combination of neutron powder diffraction and polarized neutron diffraction to give the first unambiguous assignment of its magnetic structure. Our results confirm that greigite has a collinear ferrimagnetic structure with antiferromagnetic coupling between the tetrahedral (A) and octahedral (B) sites. Our analysis also indicates that greigite d...
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The formation of pyrite (FeS2) from iron monosulfide precursors in anoxic sediments has been suggested to proceed via mackinawite (FeS) and greigite (Fe3S4). Despite decades of research, the mechanisms of pyrite formation are not sufficiently understood because solid and dissolved intermediates are oxygen-sensitive and poorly crystalline and therefore notoriously difficult to characterize and q...
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